How do we make fuels using water and sunlight?

主题:    How do we make fuels using water and  sunlight?主讲人:   王敦伟地点:   松江校区材料楼A405时间:   2016-06-13 15:30:00组织单位:   材料学院

A brief biography of Dunwei  Wang:

Dunwei Wang graduated fromthe University of Science and Technology of China  in 2000 with a B.S. degree inchemistry.  He was then trained atStanford  University (with Hongjie Dai) between 2000 and 2005, where his Ph.D.thesis was  awarded the Prize for Young Chemists by the International Union of Pure and  AppliedChemistry (2006).  Aftertwo years of postdoctoral study with James R.  Heath at Caltech, he joined thefaculty of Boston College where he is currently  an Associate Professor ofChemistry.  His research concerns thedevelopment of new  materials that can be used for efficient solar energyconversion and storage. He  has published 89 papers in Nat. Commun., J.Am. Chem. Soc., Angedw. Chem. Int.  Ed.,Int. J. Hydrogen Energy, ACS Nano, etc. He is a recipient of an NSF CAREER  award(2011), a Sloan Research Fellowship (2012), a Massachusetts CleanEnergy  Center (MassCEC) Catalyst award (2011) and a Japan Society for Promotionof  Science Fellowship (2016).

Abstract:Solar energy can be  directly harvested topower thermodynamically uphill reactions that produce  energetic chemicals,promising a large-scale energy storage and redistribution  solution.  To enable these reactions, we need materialsthat can absorb light,  separate charges, and catalyze specific chemistries.  The materials should be  made of earth-abundantelements to allow for large-scale implementations.  They  also need to be resistant against photocorrosion.  To date, a  low-cost,long-lasting material that can produce solar fuels with an  economicallymeaningful efficiency remains elusive.  Inthis talk, we present our  efforts aimed at understanding what limits thedevelopment of this important  field. Within the context of photoanode and photocathode, we show how  thephotoelectrode properties are changed by introducing material  componentsdesigned for improving charge transport, surface potential  accumulation, andinterface kinetics, respectively.  Ourresults highlight the  importance of separately understanding thermodynamic andkinetic factors in  complex systems such as that for solar fuel production.  Detailed knowledge  generated by our researchcontributes to the goal of realizing low-cost,  high-efficiency artificialphotosynthesis.




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